MIOMET

Recent Papers

2016
Affinity modulation of photoresponsive hosts for fullerenes. Light-gated corannulene tweezers
Héctor Barbero, Sergio Ferrero, Lucía Álvarez-Miguel, Patricia Gómez-Iglesias, Daniel Miguel, Celedonio M Álvarez
Chem. Commun., 2016, 52, 12964-12967.

Rigid polyurethane foams with infused nanoclays: Relationship between cellular structure and thermal conductivity
Sergio Estravis, Josias Tirado-Mediavilla, Mercedes Santiago-Calvo, Jose Luis Ruiz-Herrero, Fernando Villafañe, Miguel Angel Rodríguez-Pérez
Eur. Polym. J., 2016, 80, 1-15.

Synergistic Effect of Tetraaryl Porphyrins Containing Corannulene and Other Polycyclic Aromatic Fragments as Hosts for Fullerenes. Impact of C60 in a Statistically Distributed Mixture of Atropisomers
Celedonio M Álvarez, Héctor Barbero, Sergio Ferrero, Daniel Miguel
J. Org. Chem., 2016, 81, 14, 6081-6086.

2015
Amidino ligands obtained from the coupling of 1-methylcytosine and nitrile: a new method to incorporate biomolecules into luminescent Re(CO)3 complexes
Patricia Gómez-Iglesias, Jose M Martín-Álvarez, Daniel Miguel, Fernando Villafañe
Dalton Trans., 2015, 44, 17478-17481.

Luminescent rhenium(I) tricarbonyl complexes with pyrazolylamidino ligands: photophysical, electrochemical, and computational studies
Patricia Gómez-Iglesias, Fabrice Guyon, Abderrahim Kathyr, Gilles Ulrich, Michael Knorr, Jose M Martín-Álvarez, Daniel Miguel, Fernando Villafañe
Dalton Trans., 2015, 44, 17516-17528.

3-(Pyridin-2-yl)imidazol[1,5-a]pyridine (Pyridylindolizine) as Ligand in Complexes of transition and main-Group Metals
Celedonio M Álvarez, Lucía Álvarez-Miguel, Raúl García-Rodríguez, Jose M Martín-Álvarez, Daniel Miguel
Eur. J. Inorg. Chem., 2015, 29, 4921-4934.

Multivalent Molecular Shuttles – Effect of Increasing the Number of Centers in Switchable Catalysts
Celedonio M Álvarez, Héctor Barbero, Daniel Miguel
Eur. J. Org. Chem., 2015, 30, 6631-6640.

Assembling Nonplanar Polyaromatic Units by Click Chemistry. Study of Multicorannulene Systems as Host for Fullerenes
Celedonio M Álvarez, Gabriel Aullón, Héctor Barbero, Luis A García-Escudero, Cristina Martínez-Pérez, Jose M Martín-Álvarez, Daniel Miguel
Org. Letters, 2015, 17, 2578-2581.

2014
Structural Consequences of an Extreme Difference between the Trans Influence of the Donor Atoms in a Palladacycle
Stephan G. Koller, Raquel Martín-Romo, José S. Melero, Victoria P. Colquhoun, Daniel Schildbach, Carsten Strohmann, and Fernando Villafañe
Organometallics, 2014, 33, 7329-7332.

Pyrazolylamidino Ligands from Coupling of Acetonitrile and Pyrazoles: A Systematic Study
Patricia Gómez-Iglesias, Marta Arroyo, Sonia Bajo, Carsten Strohmann, Daniel Miguel, Fernando Villafañe
Inorg. Chem., 2014, 53, 12437-12448.

Dynamic behavior in solution of seven-coordinated transition metal complexes
Fernando Villafañe
Coord. Chem. Rev, 2014, 281, 86-99.

Enhanced association for C-70 over C-60 with a metal complex with corannulene derivate ligands
Celedonio M Alvarez, Luis A García-Escudero, Raúl García-Rodríguez, Jose M Martín-Álvarez, Daniel Miguel, Víctor M Rayón
Dalton Trans., 2014, 43, 15693-15696.

Homo- and heteropolymetallic 3-(2-pyridyl)-pyrazolate manganese and rhenium complexes
Marta Arroyo, Patricia Gómez-Iglesias, Noelia Antón, Raúl García-Rodríguez, Elisabete C.B.A. Alegria, Armando J.L. Pombeiro, Daniel Miguel, Fernando Villafañe
Dalton Trans., 2014, 43, 4009-4020.

2013
Reactivity of Silyl-Substituted Iron–Platinum Hydride Complexes toward Unsaturated Molecules: 4. Insertion of Fluorinated Aromatic Alkynes into the Platinum–Hydride Bond. Synthesis and Reactivity of Heterobimetallic Dimetallacylopentenone, Dimetallacyclobutene, μ-Vinylidene, and μ2-σ-Alkenyl Complexes
Isabelle Jourdain, Michael Knorr, Carsten Strohmann, Christian Unkelbach, Saúl Rojo, Patricia Gómez-Iglesias, and Fernando Villafañe
Organometallics, 2013, 32, 5343-5359.

Stereoselective Aldol Addition to Re(I) Complexes and Reversible Dimerization with Epimerization of the Metal Center
Celedonio M. Álvarez, Romen Carrillo, Raúl García-Rodríguez, Daniel Miguel
Chem. Eur. J., 2013, 19, 8285-8293.

Schiff plus Click: One-pot Preparation of Triazole-Substituted Iminopyridines and Ring Opening of the Triazole Ring
Celedonio M. Álvarez, Luis A. García-Escudero, Raúl García-Rodríguez and Daniel Miguel.
Dalton Trans., 2013, 42, 2556-2561. DOI: 10.1039/C2DT32400H.

2012
η6-Hexahelicene Complexes of Iridium and Ruthenium: Running along the Helix.
Celedonio M. Álvarez, Héctor Barbero, Luis A. García Escudero, Jose M. Martín-Álvarez, Cristina Martínez-Pérez, Daniel Miguel
Inorg. Chem., 2012, 51, 8103-8111.

Intramolecular carboboration of carbonyl ligands to form boroxycarbenes.
Celedonio M. Álvarez, Romen Carrillo, Raúl García-Rodríguez, Daniel Miguel
Chem. Commun., 2012, 48, 7705-7707.

Triple Bridged Anionic Dimetallic Complexes from cis-[Mo(η3-methallyl)Cl(CO)2(NCMe)2] and Pyrazolates
Fernando Lorenzo, Sonia Bajo, Daniel Miguel, Fernando Villafañe
J. Organomet. Chem., 2012, 713, 68-71

Beyond Click Chemistry: Spontaneous C-triazolyl Transfer from Copper to Rhenium and Transformation into Mesoionic  C-triazolylidene Carbene
Celedonio M. Álvarez, Luis A. García-Escudero, Raúl García-Rodríguez, Daniel Miguel
Chem Commun., 2012, 48, 7209-7211.

Coordination vs. Coupling of Dicyanamide in Molybdenum and Manganese Pyrazole Complexes
Marta  Arroyo, Patricia  Gómez-Iglesias, Jose  M. Martín-Alvarez, Celedonio M. Alvarez, Daniel Miguel, Fernando Villafañe
Inorg. Chem., 2012, 51, 6070-6080.

Complexes with 3-(pyridyne-2-yl)imidazo[1,5-a]-pyridine ligands by spontaneous dimerization of pyridine-2-carboxaldehyde within the coordination sphere of manganese(II) in a one-pot reaction.
Celedonio M. Álvarez, Lucía Álvarez-Miguel, Raúl García-Rodríguez and Daniel Miguel.
Dalton Trans., 2012, 41, 7041-7046.

Molybdenum- and tungsten(II) monometallic 3-(2-pyridyl)pyrazole and bimetallic 3-(2-pyridyl)pyrazolate complexes.
Marta Arroyo, Daniel Miguel, Fernando Villafañe, Elisabete C. B. Alegria and Armando J. L. Pombeiro
Dalton Trans., 2012, 41, 7017-7025.

Macrocycle Formation by Proton-Template-Induced Dimerization of Complexes with (Alkoxoimino)pyridine.
Celedonio M. Álvarez, Raúl García-Rodríguez, Jose M. Martín-Álvarez, Daniel Miguel and José A. Turiel
Inorg. Chem., 2012, 51, 3938-3940.

Iminopyridine complexes of manganese, rhenium and molybdenum derived from amino ester methylserine, and peptides Gly-Gly, Gly-Val, and Gly-Gly-Gly. Self-assembly of the peptide chain.
Celedonio M. Álvarez, Raúl García-Rodríguez and Daniel Miguel.
Inorg. Chem., 2012, 51, 2984-2986.

2011
pH-driven dynamic stereoinduction: epimerization upon dimerization in rhenium(I) complexes.
Celedonio M. Álvarez, Romen Carrillo, Raúl García-Rodríguez and Daniel Miguel
Chem Commun., 2011, 47, 12765-12767.

2010
Tetranuclear organometallic complexes containing Mo2O42+ and allylmolybdenum(II) moieties.
Paloma Paredes, Angel Lopez-Calzada, Daniel Miguel and Fernando Villafañe
Dalton Trans., 2010, 39, 10099-10104.

1,3,5-Tris(thiocyanatomethyl)mesitylene as a Ligand. Pseudooctahedral Molybdenum, Manganese, and Rhenium Carbonyl Complexes and Copper and Silver Dimers. Copper-Catalyzed Carbene- and Nitrene-Transfer Reactions.
Héctor Martinez-García, Dolores Morales, Julio Pérez, Marcos Puerto, and Daniel Miguel.
Inorg. Chem., 2010,49, 6974-6985.

Unexpected chemoselectivity in the Schiff condensation of amines with η2-(C,O)-η1(O)- coordinated aldehyde.
Celedonio M. Alvarez, Raul García-Rodríguez, Jose M. Martin-Alvarez and Daniel Miguel
Dalton Trans., 2010, 39, 1201-1203.

Simple 1-dicyanomethylene-2-chloro-3-aminoindene push-pull chromophores: applications in cation and anion sensing.
Sara Basurto, Daniel Miguel, Daniel Moreno, Ana G. Neo, Roberto Quesada, Tomás Torroba.
Org. and Biomol. Chem., 2010, 8, 552-558.

2009
fac-Acetato-bis(pyrazole) complexes: A systematic study on intra- and intermolecular hydrogen bonds.

Marta Arroyo, M. Teresa García-de-Prada, Carolina García Martín, Vanesa García-Pacios, Raúl García-Rodríguez, Patricia Gómez-Iglesias, Fernando Lorenzo, Isaac Martín Moreno, Daniel Miguel, Fernando Villafañe
J. Organomet. Chem., 2009, 694, 3190-3199.

Metal complexes with two different hydrogen-bond donor ligands as anion hosts.
Sonia Nieto, Julio Pérez, Lucía Riera, Víctor Riera, and Daniel Miguel
Chem. Commun., 2009, 3279-3281.

Non-covalent interactions at bis(pyrazole)silver(I) or -gold(I) cations.
Vanesa García-Pacios, Marta Arroyo, Noelia Antón, Daniel Miguel and Fernando Villafañe
Dalton Trans., 2009, 2135-2141.

Synthesis of new copper(I) complexes with tris(2-pyridyl) ligands. Applications to carbene and nitrene transfer reactions.
Julio Pérez, Dolores Morales, Luis A. García Escudero, Héctor Martínez García, Daniel Miguel and Pablo Bernad.
Dalton Trans., 2009, 375-382.

2008
Manganese cationic pyrazolylamidino complexes.

Noelia Antón, Marta Arroyo, Patricia Gómez-Iglesias, Daniel Miguel, Fernando Villafañe.
J. Organomet. Chem., 2008, 693, 3074-3080.

A new route for the synthesis of an alkylideneamido complex.
Luciano Cuesta, Dolores Morales, Julio Pérez, and Daniel Miguel
New J. Chem., 2008, 32, 917-919.

Activation of two C–H bonds of NHC N-methyl groups on triosmium and triruthenium carbonyl clusters.
Javier A. Cabeza, Ignacio del Río, Daniel Miguel, Enrique Pérez-Carreño and M. Gabriela Sánchez-Vega
Dalton Trans., 2008, 1937-1942.

Second-sphere interaction of anions with a weakly binding metal complex host: probing the effect of counteranions.
Julio Pérez, Lucía Riera, Laura Ion, Víctor Riera, Kirsty M. Anderson, Jonathan W. Steed and Daniel Miguel
Dalton Trans., 2008, 878-886.

From an N-Methyl N-Heterocyclic Carbene to Carbyne and Carbide Ligands via Multiple C-H and C-N Bond Activation.
Javier A. Cabeza, Ignacio del Río, Daniel Miguel, M. Gabriela Sánchez-Vega
Angew. Chem. Int. Ed., 2008, 47, 1920-1922.

Reactivity of N-Heterocyclic Carbenes with [Ru3(CO)12] and [Os3(CO)12]. Influence of Ligand Volume and Electronic Effects.
Javier A. Cabeza, Ignacio del Río, Daniel Miguel, Enrique-Pérez Carreño, M. Gabriela Sánchez-Vega
Organometallics, 2008, 27, 211-217.

2007
Carbonyl complexes of manganese, rhenium and molybdenum with 2-pyridylimino acid ligands.

Celedonio M. Alvarez, Raúl García-Rodríguez, Daniel Miguel
J. Organomet. Chem., 2007, 692, 5717-5726.

Synthesis and characterization of a tetraruthenium butterfly cluster containing a quadruply-bridging ligand derived from an N,N’-dipyrid-2-ylurea.
Javier A. Cabeza, Ignacio del Río, Lorena Martínez-Méndez, Daniel Miguel
J. Organomet. Chem., 2007, 692, 4407-4410.

Mononuclear ruthenium complexes containing chiral aminooxazolines: Syntheses, X-ray studies and catalytic activity.
Javier A. Cabeza, Iván da Silva, Ignacio del Río, Robert A. Gossage, Lorena Martínez-Méndez, Daniel Miguel.
J. Organomet. Chem., 2007, 692, 4346-4352.

Pyridine-2-carboxaldehyde as ligand: Synthesis and derivatization of carbonyl complexes.
Celedonio M. Alvarez, Raul García-Rodríguez and Daniel Miguel
Dalton Trans., 2007, 3546-3554.

High-Nuclearity Osmium Carbonyl Cluster Complexes Containing (6-Methylpyrid-2-yl)imido Ligands. Synthesis of Hepta-, Octa-, and Nonanuclear Derivatives.
Javier A. Cabeza, Ignacio del Río, Pablo García-Alvarez, and Daniel Miguel
Organometallics, 2007, 26, 3212-3216.

A new coordination mode for (pyrid-2-yl)thiolate (L) ligands: Synthesis and characterization of [Ru63-H)(μ5-k2-L)(μ-CO)(CO)15].
Javier A. Cabeza, Ignacio del Río,  Pablo García-Alvarez, Daniel Miguel
J. Organomet. Chem., 2007, 692, 3583-3587.

Pyrazole Complexes as Anion Receptors: Effects of Changing the Metal, the Pyrazole Substitution Pattern, and the Number of Pyrazole Ligands.
Sonia Nieto, Julio Pérez, Lucía Riera, Víctor Riera, Daniel Miguel, James A. Golen, and Arnold L. Rheingold
Inorg. Chem., 2007, 46, 3407-3418.

Ruthenium Cluster Mediated Transformation of Linear Alkenes into Trienyl Ligands. Activation of Five C(sp3)-H Bonds of 1-Octene, 1-Nonene, and 1-Decene.
Javier A. Cabeza, Ignacio del Río, Pablo García Álvarez, and Daniel Miguel
Organometallics, 2007, 26, 2482-2484.

Biimidazole and Bis(amide)bipyridine Molybdenum Carbonyl Complexes as Anions Receptors.
Laura Ion, Dolores Morales, Sonia Nieto,  Julio Pérez, Lucía Riera, Víctor Riera, Daniel Miguel, Richard A. Kowenicki, Mary McPartlin
Inorg. Chem., 2007, 46, 2846-2853.

Synthesis, Structure and Reactivity of Mononuclear Re(I) Oximato Complexes.
Luciano Cuesta, Miguel A. Huertos, Dolores Morales,  Julio Pérez, Lucía Riera, Víctor Riera, Daniel Miguel, Amador Menéndez-Velázquez, Santiago García-Granda.
Inorg. Chem., 2007, 46, 2836-2845.

Reactivity of Indene, Fluorene, Azulene, and Acenaphthylene with a Basal-Edge-Bridged. Square-Pyramidal Hexaruthenium Dihydride.
Javier A. Cabeza, Ignacio del Río, Jose M. Fernandez-Colinas Pablo García-Álvarez, Daniel Miguel.
Organometallics, 2007, 26, 1414-1426.

2006
Nonanuclear Ruthenium Carbonyl Cluster Complexes with a Novel Metallic Skeleton: Pentagonal Bipyramid with two Equatorial Edges Spanned by Metal Atoms

J. A. Cabeza, I. del Río, P. García-Álvarez, D. Miguel.
Organometallics, 2006, 25, 5672-5675.

Synthesis and Reactivity of New Methoxymethyl Complexes of Manganese(I) and Rhenium(I).
E. Hevia, D. Miguel, J. Pérez, and V. Riera.
Organometallics, 2006, 25, 4909-4912.

Second-sphere coordination complex via hydrogen bonding: Synthesis, characterization, X-ray crystal structure determination and packing of  hexaamminecobalt(III) chloride di(para-dinitrobenzoate).
R. P. Sharma, R. Bala, R. Sharma, J. Pérez, and D. Miguel.
J. Mol. Struct., 2006, 797, 49-55.

Rhenium-Mediated Coupling of Acetonitrile and Pyrazoles. New Molecular Clefts for Anion Binding.
M. Arroyo, D. Miguel, F. Villafañe, S. Nieto, J. Pérez, and L. Riera
Inorg. Chem., 2006, 45, 7018-7026.

High-Nuclearity Ruthenium Carbonyl Cluster Complexes Derived from 2-Amino-6-methylpyridine: Synthesis of Nonanuclear Derivatives Containing µ4– and µ5-Oxo Ligands.
J. A. Cabeza, I. del Río, P. García-Álvarez, D. Miguel.
Inorg. Chem., 2006, 45, 6020-6027.

Second-sphere coordination complexes via hydrogen bonding: Synthesis, characterization of [Co(NH3)6](XO3)3.nH2O (X = Br, I) and single crystal X-ray structure determination of  [Co(NH3)6](BrO3)3.0.5H2O
R. P. Sharma, R. Bala, R. Sharma, J. Pérez, and D. Miguel.
J. Mol. Struct., 2006, 788, 49-54.

Carbonyl complexes of manganese, rhenium and molybdenum with ethynyliminopyridine ligands.
L. A. García-Escudero, D. Miguel and J. A. Turiel.
J. Organomet. Chem.,  2006, 691, 3434-3444.

Non-covalent interactions between anions and a cationic rheniun diamine complex: structural characterization of the supramolecular adducts.
S. Nieto, J. Pérez,  L. Riera, V. Riera,  and D. Miguel.
New J. Chem., 2006, 30, 838-841.

Triruthenium carbonyl clusters derived from chiral aminooxazolines: synthesis and catalytic activity.
J. A. Cabeza, I. da Silva, I. del Río, R. A. Gossage, D. Miguel and M. Suarez.
Dalton Trans., 2006, 2450-2455.

Reactivity of Arenes, Cycloheptatriene, and Dicyclopentadiene with a basal Edge-Bridged Square Pyramidal Hexaruthenium Dihydride.
J. A. Cabeza, I. del Río, P. García-Álvarez, D. Miguel.
Organometallics, 2006, 25, 2683-2692.

Reactivity of Molybdenum and Rhenium Hydroxo Complexes toward Organic Electrophiles: Reactions that Afford Carboxylato Products
L. Cuesta, E. Hevia, D. Morales, J. Pérez, L. Riera and D. Miguel,
Organometallics, 2006, 25, 1717-1722.

Pyrazole Complexes as anion receptors
S. Nieto, J. Pérez, L. Riera, V. Riera and D. Miguel,
Chem. Eur. J., 2006, 12, 2244-2251.

Hexaruthenium and octaruthenium carbonyl cluster complexes derived from 2-amino-6- methylpyridine. Novel coordination modes for 2-imidopyridines
J. A. Cabeza, I. del Río, P. García-Álvarez, D. Miguel.
Can. J. Chem.,  2006, 84, 105-110.

Reactivity of Diphenylbutadiyne with a Hexaruthenium Dihydride. Unusual 1,1- and trans-1,2-Additions of Two Hydrogen Atoms to an Internal CC Triple Bond
J. A. Cabeza, I. del Río, J. M. Fernández-Colinas, P. García-Álvarez and D. Miguel
Organometallics, 2006, 25, 1492-1499.

Molybdenum carbonyl complexes with pyridylimino acidato ligands
Raúl Garcia Rodriguez, Daniel Miguel
Dalton Trans., 2006, 1218-1225

Ruthenium cluster mediated activation of all bonds of methyl groups of 6,6’-dimethyl-2,2’-bipyridine and 2,9-dimethyl-1,10-phenantroline. Transformation of the latter into a 2-alkenyl-9-methyl-1,10-phenantroline ligand
Javier A. Cabeza, Ignacio del Río, Lorena Martínez Méndez, Daniel Miguel
Chem. Eur. J.,  2006, 12, 1529-1538

2005
From Cyclopentanone Oximes to Bis[1,2,3]dithiazolo-s-indacenes, Cyclopenta[c][1,2]thiazine, Pentathiepino-, Tetrathiino-, and Thienocyclopenta[1,2,3] dithiazoles as a Rich Source of New Materials.

Sonia Macho, Daniel Miguel, Teresa Gómez,TeresaRodríguez, TomasTorroba
J Org. Chem.,  2005, 70, 9314-9325

Cyclopentathiadiazines, Cyclohepta- and Cyclopentadithiazoles: New Materials and a Rich Heterocyclic Chemistry of Cyclic Enaminonitriles
Teresa Gómez, Sonia Macho, Daniel Miguel, Ana G. Neo, Teresa Rodríguez, Tomás Torroba
Eur. J. Org. Chem., 2005, 5055-5066

Pyrazolylamidino and Bis(pyrazole)manganese(I) complexes.
Marta Arroyo, Alvaro López-Sanvicente, Daniel Miguel, Fernando Villafañe
Eur. J. Inorg. Chem., 2005, 4430-4437

Indene and pseudoazulene discotic liquid crystals: a synthetic and structural study.
Sara Basurto, Susana García, Ana G. Neo, Tomás Torroba, Carlos F. Marcos, Daniel Miguel, Joaquín Barberá, M. Blanca Ros, M. Rosario de la Fuente
Chem.Eur. J.,  2005, 11, 5362-5376

Easy activation of two C-H bonds of an N-heterocyclic carbene N-methyl group.
Javier A. Cabeza, Ignacio del Rio, Daniel Miguel, M. Gabriela Sánchez-Vega
Chem. Commun., 2005, 3956-3958

Activation of ancillary ligands in the reactions of DMAD with phosphido and alkylideneamido rhenium complexes
Luciano Cuesta, Eva Hevia, Dolores Morales, Julio Pérez; Víctor Riera; Markus Seitz, Daniel Miguel
Organometallics, 2005, 24, 1772-1775

New [Mo(h3-allyl)(CO)2L3]+ complexes with monodentate or tridentate nitrogen-donor ligands
Julio Pérez, Dolores Morales, Sonia Nieto, Lucía Riera, Víctor Riera, Daniel Miguel and Celedonio Alvarez
Dalton Trans., 2005, 884-888

Reactivity of Diphenylacetylene with a Basal Edge-Bridged Square-Pyramidal Hexaruthenium Cluster. Characterization of Penta-, Hexa-, and Heptanuclear Alkyne Derivatives.
Javier A. Cabeza, Ignacio del Rio, Pablo García-Alvarez, Daniel Miguel.
Organometallics, 2005, 24, 665-674

Cationic fac-tris(pyrazole) complexes as anion receptors
Sonia Nieto, Julio Pérez, Víctor Riera, Daniel Miguel and Celedonio Alvarez
Chem.Comm., 2005, 546-548

Cyclopentathiadiazines, new heterocyclic materials from cyclic enaminonitriles
Sonia Macho, Daniel Miguel, Ana G. Neo, Teresa Rodríguez and Tomás Torroba
Chem.Comm., 2005, 334-336

Activation of a 1,10-phenanthroline ligand on a rhenium tricarbonyl complex.
LucianoCuesta, Eva Hevia, Dolores Morales, Julio Pérez, Víctor Riera, Elena Rodríguez and Daniel Miguel
Chem.Comm., 2005, 116-117

2004
Hexaruthenium Carbonyl Cluster Complexes with basal edge-bridged square pyramidal metallic skeleton: efficient synthesis of 2-iminopyridine derivatives and determination of their reactive sites in carbonyl substitution reactions.

Javier A. Cabeza,  Ignacio del Río, Pablo García-Álvarez, Daniel Miguel, Víctor Riera
Inorg. Chem., 2004, 43, 5450-5458

Activation of all bonds of a methyl group attached to an organic fragment.
Javier A. Cabeza, Iván da Silva, Ignacio del Río, Lorena Martínez Méndez, Daniel Miguel, Víctor Riera
Angew. Chem. Int. Ed., 2004, 43, 3464-3467

Alkyl transfer reactivity in the first octahedral Isocyanide complex of nickel (II)
Enmanuel Boíllos, Daniel Miguel
Organometallics, 2004, 23, 2568-2572

Alkylation and metallation of binuclear anions caontaining a novel tricyclohexylphosphonioethanetrithiolate ligand  homodinuclear complex of manganese containing novel ligand, S(SR)C=C(PCy3)S}.
Yon Qiang Ma, Ning Yin,  Jing Li, Quing-lan Xie, Daniel Miguel
J. Organomet. Chem., 2004, 689, 1949-1955

A neutral organometallic fluoro complex can be a good ligand.
Laurent Coue, Luciano Cuesta, Dolores Morales, Jason A: Halfen, Julio Pérez, Lucía Riera, Víctor Riera, Daniel Miguel, Neil G. Connelly, Supakorn Boonyuen.
Chem. Eur. J., 2004, 10, 1906-1912

Reactivity of Molybdenum and Rhenium Hydroxo-Carbonyl Complexes toward Organic Electrophiles
Luciano Cuesta, Darío C. Gerbino, Eva Hevia, Dolores Morales, M. Elena Navarro-Clemente, Julio Pérez, Lucía Riera, Víctor Riera, Daniel Miguel, Igancio del Río, Santiago García-Granda
Chem. Eur. J., 2004, 10, 1765-1777